Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)

Cassin, Savannah R, Flynn, Sean ORCID: 0000-0001-6028-3389, Chambon, Pierre and Rannard, Steve P ORCID: 0000-0002-6946-1097 (2021) Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT). RSC ADVANCES, 11 (39). pp. 24374-24380. ISSN 2046-2069, 2046-2069

Access the full-text of this item by clicking on the Open Access link.

Abstract

New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure-property relationships. Here we present a detailed inverse gated ¹³C NMR characterisation of materials derived from the very recently reported Transfer-dominated Branching Radical Telomerisation (TBRT) approach to quantify branching and provide an insight into cyclisation.

Item Type:	Article
Uncontrolled Keywords:	3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	09 Aug 2021 10:46
Last Modified:	06 Dec 2024 21:06
DOI:	10.1039/d1ra03886a
Open Access URL:	https://pubs.rsc.org/en/content/articlehtml/2021/r...
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3132902