Plasma synthesis of ammonia in a tangled wire dielectric barrier discharge reactor: Effect of electrode materials

Ma, Y ORCID: 0000-0002-4404-8714, Tian, Y ORCID: 0000-0002-6445-4031, Zeng, Y and Tu, X ORCID: 0000-0002-6376-0897 (2021) Plasma synthesis of ammonia in a tangled wire dielectric barrier discharge reactor: Effect of electrode materials Journal of the Energy Institute, 99. pp. 137-144. ISSN 1743-9671, 1746-0220

Text 1.pdf - Author Accepted Manuscript Download (3MB) | Preview

Abstract

Plasma synthesis of NH<inf>3</inf> from N<inf>2</inf> and renewable H<inf>2</inf> under mild conditions is very attractive for decentralised sustainable green ammonia production using intermittent renewables. In this study, NH<inf>3</inf> synthesis was performed under ambient conditions in a dielectric barrier discharge (DBD) plasma reactor. Different tangled wire internal electrodes were employed to understand the influence of electrode materials on plasma ammonia synthesis. Compared with a rod electrode, a tangled wire electrode substantially enhanced the NH<inf>3</inf> concentration and reduced the energy cost for ammonia production, which can be attributed to the expanded surface area and the chemisorption properties of the tangled electrodes. The influence of the N<inf>2</inf>/H<inf>2</inf> molar ratio and total flow rate on the reaction performance was also evaluated. The lowest energy cost (59.0 MJ mol⁻¹) for ammonia production was achieved using a Cu tangled electrode at a total flow rate of 250 ml min⁻¹ and a discharge power of 20 W. The electrical diagnostics of the plasma process showed that the tangled wire electrodes decreased the breakdown voltage of the DBD and enhanced charge deposition, which enhanced the NH<inf>3</inf> production. The reaction mechanism was discussed for the process optimisation of ammonia synthesis in a tangled wire DBD system.

Item Type:	Article
Uncontrolled Keywords:	Ammonia synthesis, Dielectric barrier discharge, Non-thermal plasma, Electrode materials, Nitrogen fixation
Divisions:	Faculty of Science & Engineering > School of Electrical Engineering, Electronics and Computer Science
Depositing User:	Symplectic Admin
Date Deposited:	10 Sep 2021 07:18
Last Modified:	01 Mar 2026 11:53
DOI:	10.1016/j.joei.2021.09.002
Related Websites:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3136516
Disclaimer:	The University of Liverpool is not responsible for content contained on other websites from links within repository metadata. Please contact us if you notice anything that appears incorrect or inappropriate.