High-Throughput Discovery of a Rhombohedral Twelve-Connected Zirconium-Based Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers


Tollitt, Adam M ORCID: 0000-0001-9470-6095, Vismara, Rebecca, Daniels, Luke M ORCID: 0000-0002-7077-6125, Antypov, Dmytro ORCID: 0000-0003-1893-7785, Gaultois, Michael W ORCID: 0000-0003-2172-2507, Katsoulidis, Alexandros P ORCID: 0000-0003-0860-7440 and Rosseinsky, Matthew J ORCID: 0000-0002-1910-2483 (2021) High-Throughput Discovery of a Rhombohedral Twelve-Connected Zirconium-Based Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60 (52). pp. 26939-26946. ISSN 1433-7851, 1521-3773

[thumbnail of Zr_tere_fum_paper_accepted version.docx] Text
Zr_tere_fum_paper_accepted version.docx - Author Accepted Manuscript
Download (17MB)

Abstract

We report a metal-organic framework where an ordered array of two linkers with differing length and geometry connect [Zr<sub>6</sub> (OH)<sub>4</sub> O<sub>4</sub> ]<sup>12+</sup> clusters into a twelve-connected fcu net that is rhombohedrally distorted from cubic symmetry. The ordered binding of equal numbers of terephthalate and fumarate ditopic carboxylate linkers at the trigonal antiprismatic Zr<sub>6</sub> core creates close-packed layers of fumarate-connected clusters that are connected along the single remaining threefold axis by terephthalates. This well-defined linker arrangement retains the three-dimensional porosity of the Zr cluster-based UiO family while creating two distinct windows within the channels that define two distinct guest diffusion paths. The ordered material is accessed by a restricted combination of composition and process parameters that were identified by high-throughput synthesis.

Item Type: Article
Uncontrolled Keywords: chemical space, high-throughput synthesis, Metal-organic frameworks, ordered linkers, rhombohedral distortion
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 10 Sep 2021 09:55
Last Modified: 07 Dec 2024 22:59
DOI: 10.1002/anie.202108150
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3136610
Altmetric
Share
CORE (COnnecting REpositories)