Hydrodeoxygenation of 2,5-dimethyltetrahydrofuran over bifunctional Pt-Cs2.5H0.5PW12O40 catalyst in the gas phase: enhancing effect of gold


Althikrallah, Hanan, Kozhevnikova, Elena F ORCID: 0000-0001-8242-7945 and Kozhevnikov, Ivan V ORCID: 0000-0003-2453-5256 (2022) Hydrodeoxygenation of 2,5-dimethyltetrahydrofuran over bifunctional Pt-Cs2.5H0.5PW12O40 catalyst in the gas phase: enhancing effect of gold. RSC ADVANCES, 12 (4). pp. 2287-2291. ISSN 2046-2069, 2046-2069

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Abstract

2,5-Dimethyltetrahydrofuran (DMTHF) is deoxygenated to <i>n</i>-hexane with >99% selectivity at mild conditions (90 °C, 1 bar H<sub>2</sub> pressure, fixed-bed reactor) in the presence of the bifunctional metal-acid catalyst Pt-CsPW comprising Pt and Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub> (CsPW), an acidic Cs salt of Keggin-type heteropoly acid H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>. Addition of gold to the Pt-CsPW catalyst increases the turnover rate at Pt sites more than twofold, whereas the Au alone without Pt is not active. The enhancement of catalyst activity is attributed to PtAu alloying, which is supported by STEM-EDX and XRD analysis.

Item Type: Article
Uncontrolled Keywords: 34 Chemical Sciences
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 08 Mar 2022 11:33
Last Modified: 07 Dec 2024 23:24
DOI: 10.1039/d1ra09105k
Open Access URL: https://doi.org/10.1039/D1RA09105K
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3150358
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