Herklotz, F, Lavrov, EV, Hobson, TDC, Major, JD 
ORCID: 0000-0002-5554-1985 and Durose, K ORCID: 0000-0003-1183-3211
(2022)
Oxygen in antimony triselenide: An IR absorption study.
APPLIED PHYSICS LETTERS, 120 (21).
212101-.
ISSN 0003-6951, 1077-3118
|
Text
Herklotz paper.pdf - Author Accepted Manuscript Download (202kB) | Preview |
Abstract
<jats:p>Oxygen in single crystalline antimony triselenide (Sb2Se3) is addressed by infrared (IR) absorption spectroscopy. Measurements conducted on Sb2Se3 samples doped—during growth, post-growth annealing in the O2 ambient, or by O ion implantation—with 16O reveal an IR absorption line at 527 cm−1 (10 K). Substitution of 16O by 18O “red”-shifts the signal down to 500 cm−1 based on which the line is assigned to a local vibrational mode of an isolated oxygen defect. Annealing of O-enriched samples in hydrogen atmosphere at temperatures above 380 °C results in the suppression of the 527-cm−1 line and concurrent appearance of the signals due to hydroxyl groups, suggesting formation of oxygen-hydrogen complexes. The configuration of the 527-cm−1 oxygen center is discussed.</jats:p>
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 51 Physical Sciences |
| Divisions: | Faculty of Science and Engineering > School of Physical Sciences |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 27 Jun 2022 09:30 |
| Last Modified: | 06 Dec 2024 21:36 |
| DOI: | 10.1063/5.0095547 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3157304 |
Altmetric
Altmetric
