Unprecedented Convergent Synthesis of Sugar-Functionalization of Phosphinic Acids under Metal-Free Conditions



Abdou, Moaz M, O'Neill, Paul M, Amigues, Eric and Matziari, Magdalini
(2022) Unprecedented Convergent Synthesis of Sugar-Functionalization of Phosphinic Acids under Metal-Free Conditions. ACS OMEGA, 7 (25). pp. 21444-21453.

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Abstract

A novel TEA-catalyzed sugar-esterification of phosphinic acids was used as a general and efficient approach for the synthesis of a variety of phosphinates without any transition metal. The high efficiency of the current methodology and a convenient experimental procedure compensate for the moderate yields obtained. Another advantage is that the reaction tolerates different substituents attached to the phosphinic acids and the sugar moieties alongside the ease of isolation of the product.

Item Type: Article
Uncontrolled Keywords: 3402 Inorganic Chemistry, 3405 Organic Chemistry, 34 Chemical Sciences
Depositing User: Symplectic Admin
Date Deposited: 13 Jul 2022 13:59
Last Modified: 22 Jun 2024 15:42
DOI: 10.1021/acsomega.2c00712
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3158388