Charge carrier absorption in <i>n</i>-type Sb2Se3



Herklotz, F ORCID: 0000-0002-8705-6917, Lavrov, EV ORCID: 0000-0002-1480-4240, Hobson, TDC ORCID: 0000-0002-0013-360X, Major, JD ORCID: 0000-0002-5554-1985 and Durose, K ORCID: 0000-0003-1183-3211
(2024) Charge carrier absorption in <i>n</i>-type Sb2Se3. Applied Physics Letters, 125 (12). 122104-. ISSN 0003-6951, 1077-3118

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Abstract

<jats:p>The optical and electrical properties of n-type chlorine-doped Sb2Se3 single crystals, with free carrier concentrations above 1016 cm−3 at room temperature, have been studied. The experiments reveal a strongly polarized temperature-dependent long-wavelength infrared absorption attributable to conduction band electrons within the material. For wavelengths between 1.6 and 6 μm, the room temperature absorption varies as λ2.5±0.3, suggesting that longitudinal optical mode scattering is the dominant electron scattering mechanism. The results are most consistent with the hypothesis that electron transport in Sb2Se3 is band-like and not intrinsically limited by small-polaron self-trapping.</jats:p>

Item Type: Article
Uncontrolled Keywords: 51 Physical Sciences, 40 Engineering, 4018 Nanotechnology
Divisions: Faculty of Science and Engineering
Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 04 Jun 2025 14:51
Last Modified: 05 Aug 2025 16:11
DOI: 10.1063/5.0222193
Open Access URL: https://pubs.aip.org/aip/apl/article/125/12/122104...
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3188134