Lewis, Bradley G
ORCID: 0009-0008-9185-2343, Bahri, Mounib
ORCID: 0000-0002-8336-9158, Shalvey, Thomas P
ORCID: 0000-0002-6008-7561, Hobson, Theodore DC, Lee, Yeon, Leighton, Chris, Durose, Ken
ORCID: 0000-0003-1183-3211, Browning, Nigel and Major, Jonathan D
ORCID: 0000-0002-5554-1985
(2025)
Role of the Seed and Electron Transport Layers in GeSe Thin Film Photovoltaics.
Solar RRL, 9 (17).
ISSN 2367-198X, 2367-198X
Abstract
<jats:p>This work investigates the use of closed‐spaced sublimation for deposition of GeSe thin films for photovoltaics. Film quality was optimised via an in situ substrate annealing process for the production of functioning devices. The influence of both and CdS electron transport layers (ETLs) was studied both with and without the addition of an seed layer. Besides enabling high power conversion efficiencies (PCEs), the role of the seed layer was studied and a beneficial modification to subsequent GeSe growth was found. In addition to this, a large contribution to light absorption and photocurrent generation was found for layers thicker than 50 nm. Devices with a reduced thickness seed layer down to 2 nm were fabricated in which ETL devices out‐performed those with CdS for PCE up to 1.75%.</jats:p>
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 40 Engineering, 4016 Materials Engineering |
| Divisions: | Faculty of Science and Engineering Faculty of Science and Engineering > School of Engineering Faculty of Science and Engineering > School of Physical Sciences |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 27 Aug 2025 08:10 |
| Last Modified: | 25 Sep 2025 15:15 |
| DOI: | 10.1002/solr.202500347 |
| Open Access URL: | https://doi.org/10.1002/solr.202500347 |
| Related Websites: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3194162 |
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