Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts

Gee, Jack C, Fuller, Beth A, Lockett, Hannah-Marie, Sedghi, Gita, Robertson, Craig M ORCID: 0000-0002-4789-7607 and Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139 (2018) Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts. CHEMICAL COMMUNICATIONS, 54 (68). pp. 9450-9453.

	Text 2. pt-adcs-photocatalysis_017-ccomm.pdf - Author Accepted Manuscript Download (1MB)
	Text 3. si-pt-adcs-photocatalysis_015-comm.pdf - Author Accepted Manuscript Download (7MB)

Abstract

Platinum-[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.

Item Type:	Article
Depositing User:	Symplectic Admin
Date Deposited:	02 Aug 2018 06:32
Last Modified:	19 Jan 2023 01:29
DOI:	10.1039/c8cc04287j
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3024469

Available Versions of this Item

• Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts. (deposited 27 Jul 2018 11:33)
  • Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts. (deposited 02 Aug 2018 06:32) [Currently Displayed]