Metal/molecule/metal junction studies of organometallic and coordination complexes; What can transition metals do for molecular electronics?

Higgins, Simon J ORCID: 0000-0003-3518-9061 and Nichols, Richard J ORCID: 0000-0002-1446-8275 (2018) Metal/molecule/metal junction studies of organometallic and coordination complexes; What can transition metals do for molecular electronics? POLYHEDRON, 140. pp. 25-34.

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Official URL: http://dx.doi.org/10.1016/j.poly.2017.10.022

Abstract

The science of ‘molecular’ electronics has been stimulated by the evolution of reliable techniques for fabricating and testing metal/single molecule/metal junctions over the last fifteen years. Transition metals offer the possibilities of redox activity, stable paramagnetic states and, in some cases, relatively narrow HOMO−LUMO separation, factors that make them of interest for incorporation into such junctions. In this short review, we describe our progress to develop reliable contacts for organometallic molecular wires, to test the effects of incorporating metal centres into molecular wires, and to examine the electrochemical gating of redox-active coordination complexes.

Item Type:	Article
Uncontrolled Keywords:	Molecular electronics, Single molecule junctions, Metal-alkynyl complexes, Metal-terpyridine complexes
Depositing User:	Symplectic Admin
Date Deposited:	12 Sep 2018 07:11
Last Modified:	19 Jan 2023 01:18
DOI:	10.1016/j.poly.2017.10.022
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3026131