Reactivity of acyclic diaminocarbene ligands

Kinzhalov, Mikhail A and Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139 (2019) Reactivity of acyclic diaminocarbene ligands. COORDINATION CHEMISTRY REVIEWS, 399. p. 213014.

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Abstract

Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in organometallic chemistry, catalysis, photophysics and crystal engineering. Although the preparation and application of metal-ADC species are discussed in many reports, the reactivity of ADC ligands is much less scrutinised. However, studies emerged indicate that ADC ligands, in particular, those prepared via the metal-mediated nucleophilic addition to isocyanides, can be further converted into various post-functionalised derivatives. In this review, we attempt for the first time to rationalise the most important reactivity modes of metal-ADC species reported up to date.

Item Type:	Article
Uncontrolled Keywords:	Acyclic diaminocarbene, Carbene ligands, Reactivity modes, Metal complexes, Deprotonation
Depositing User:	Symplectic Admin
Date Deposited:	09 Oct 2019 12:36
Last Modified:	19 Jan 2023 00:23
DOI:	10.1016/j.ccr.2019.213014
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3057584