Coletta, Marco, McLellan, Ross, Murphy, Paul, Leube, Bernhard T, Sanz, Sergio, Clowes, Rob, Gagnon, Kevin J, Teat, Simon J, Cooper, Andrew I 
ORCID: 0000-0003-0201-1021, Paterson, Martin J et al (show 2 more authors)
(2016)
Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal-Organic Trigonal Antiprism.
CHEMISTRY-A EUROPEAN JOURNAL, 22 (26).
pp. 8791-8795.
Abstract
Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis-C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal-organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N2 or H2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | calixarenes, clusters, directed assembly, gas storage, metal-organic polyhedron |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 30 Jan 2020 13:43 |
| Last Modified: | 19 Jan 2023 00:05 |
| DOI: | 10.1002/chem.201600762 |
| Open Access URL: | https://www.pure.ed.ac.uk/ws/files/28342922/Bis_Ca... |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3072695 |
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