Althikrallah, Hanan ORCID: 0000-0002-5098-3696, Kozhevnikova, Elena F and Kozhevnikov, Ivan V ORCID: 0000-0003-2453-5256
(2021)
Facile gas-phase hydrodeoxygenation of 2,5-dimethylfuran over bifunctional metal-acid catalyst Pt-Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub>.
CHEMICAL COMMUNICATIONS, 57 (2).
pp. 227-230.
Text
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Abstract
2,5-Dimethylfuran is deoxygenated to n-hexane with 100% yield on a bifunctional Pt/C-Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub> catalyst under very mild conditions (90 °C, 1 bar H<sub>2</sub>) in a one-step gas-phase process. A proposed mechanism includes a sequence of hydrogenolysis, hydrogenation and dehydration steps occurring on Pt and proton sites of the bifunctional catalyst.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 18 Dec 2020 13:56 |
Last Modified: | 08 Oct 2023 15:18 |
DOI: | 10.1039/d0cc06934e |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3110788 |