Band offsets of metal oxide contacts on TlBr radiation detectors



Voyce, Olivia K, Isaacs, Mark A, Harkness-Brennan, Laura J, Veal, Tim D ORCID: 0000-0002-0610-5626, Judson, Dan S, Motakef, Shariar and Datta, Amlan
(2021) Band offsets of metal oxide contacts on TlBr radiation detectors. JOURNAL OF APPLIED PHYSICS, 130 (17). 175305-.

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Abstract

<jats:p>Metal oxides are investigated as an alternative to metal contacts on thallium bromide (TlBr) radiation detectors. X-ray photoelectron spectroscopy studies of SnO2/TlBr and ITO/TlBr devices indicate that a type-II staggered heterojunction forms between TlBr and metal oxides upon contacting. By using the Kraut method of valence band offset (VBO) determination, the VBOs of SnO2/TlBr and ITO/TlBr heterojunctions are determined to be 1.05±0.17 and 0.70±0.17 eV, respectively. The corresponding conduction band offsets are then found to be 0.13±0.17 and 0.45±0.17 eV, respectively. The I–V response of symmetric In/SnO2/TlBr and In/ITO/TlBr planar devices is almost Ohmic with a leakage current of less than 2.5 nA at 100 V.</jats:p>

Item Type: Article
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 18 Oct 2021 07:12
Last Modified: 15 Mar 2024 04:49
DOI: 10.1063/5.0063365
Open Access URL: https://aip.scitation.org/doi/10.1063/5.0063365
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3140747