Irradiation Behaviour of High Entropy Alloys



Fu, Honglun
(2022) Irradiation Behaviour of High Entropy Alloys. PhD thesis, University of Liverpool.

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Abstract

Four high entropy alloys (HEA), CoCrCuFeNi, Co1.5CrFeNi1.5Ti0.5Mo0.1, both adopting an FCC structure, and TaNbHfZrTi, and AlCoCrFeNiSi, adopting a BCC structure, have been irradiated with He and 3 MeV Ni ions, as part of the process of understanding their application within fission based nuclear reactors. When irradiated nano-indentation analysis shows that the FCC and BCC respond differently. The FCC phases show a decrease in hardness with increasing ion fluence, for example at depth of 100nm CoCrCuFeNi shows a decrease from ~7.5 GPa to ~4.5 GPa. However, the BCC phases show an initial increase in hardness with ion fluence, for example at a depth of 100nm TaNbHfZrTi, shows an intial increase from ~9.5 GPa to ~ 10.2 GPa, with a subsequent drop to ~8.75 GPa. Transmission electron microscopy based analysis shows that ion beam induced damage is visible in the samples, with 3 MeV Ni inducing differing levels of visible damage. Analysis of He irradiated samples suggests that there might be beginnings of bubble formation, but the evidence is not clear cut.

Item Type: Thesis (PhD)
Divisions: Faculty of Science and Engineering > School of Engineering
Depositing User: Symplectic Admin
Date Deposited: 14 Apr 2022 15:06
Last Modified: 18 Jan 2023 21:05
DOI: 10.17638/03152332
Supervisors:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3152332