Looking deep into C-H functionalization: the synthesis and application of cyclopentadienyl and related metal catalysts

Jardim, Guilherme AM, de Carvalho, Renato L ORCID: 0000-0002-8515-9306, Nunes, Mateus P, Machado, Luana A, Almeida, Leandro D, Bahou, Karim A, Bower, John F ORCID: 0000-0002-7551-8221 and da Silva Junior, Eufranio N (2022) Looking deep into C-H functionalization: the synthesis and application of cyclopentadienyl and related metal catalysts. CHEMICAL COMMUNICATIONS, 58 (19). pp. 3101-3121.

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Abstract

Metal catalyzed C-H functionalization offers a versatile platform for methodology development and a wide variety of reactions now exist for the chemo- and site-selective functionalization of organic molecules. Cyclopentadienyl-metal (CpM) complexes of transition metals and their correlative analogues have found widespread application in this area, and herein we highlight several key applications of commonly used transition-metal Cp-type catalysts. In addition, an understanding of transition metal Cp-type catalyst synthesis is important, particularly where modifications to the catalyst structure are required for different applications, and a summary of this aspect is given.

Item Type:	Article
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	01 Feb 2022 13:51
Last Modified:	15 Apr 2024 10:25
DOI:	10.1039/d1cc07040a
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3147955