Walsh, James J, Forster, Mark ORCID: 0000-0002-8077-7690, Smith, Charlotte L, Neri, Gaia ORCID: 0000-0003-1326-9327, Potter, Richard J ORCID: 0000-0003-0896-4536 and Cowan, Alexander J ORCID: 0000-0001-9032-3548
(2018)
Directing the mechanism of CO<sub>2</sub> reduction by a Mn catalyst through surface immobilization.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 20 (10).
pp. 6811-6816.
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Mn_TiO2 JJW PCCP.pdf - Author Accepted Manuscript Download (1MB) |
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Mn_TiO2 JJW PCCP ESI.pdf - Author Accepted Manuscript Download (1MB) |
Abstract
Immobilization of a Mn polypyridyl CO<sub>2</sub> reduction electrocatalyst on nanocrystalline TiO<sub>2</sub> electrodes yields an active heterogeneous system and also significantly triggers a change in voltammetric and catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are presented here to elucidate the mechanism of the immobilized catalyst in situ.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 22 Feb 2018 15:23 |
Last Modified: | 06 Feb 2024 23:22 |
DOI: | 10.1039/c7cp08537k |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3018332 |