Wu, Yue 
ORCID: 0000-0003-2874-8267, Halat, David M, Wei, Fengxia, Binford, Trevor, Seymour, Ieuan D, Gaultois, Michael W ORCID: 0000-0003-2172-2507, Shaker, Sammy, Wang, John, Grey, Clare P and Cheetham, Anthony K
(2018)
Mixed X-Site Formate-Hypophosphite Hybrid Perovskites.
CHEMISTRY-A EUROPEAN JOURNAL, 24 (44).
pp. 11309-11313.
Abstract
Following the recent discovery of a new family of hybrid ABX<sub>3</sub> perovskites where X=(H<sub>2</sub> POO)<sup>-</sup> (hypophosphite), this work reports a facile synthesis for mixed X-site formate perovskites of composition [GUA]Mn(HCOO)<sub>3-x</sub> (H<sub>2</sub> POO)<sub>x</sub> , with two crystallographically distinct, partially ordered intermediate phases with x=0.84 and 1.53, corresponding to ca. 30 and 50 mol % hypophosphite, respectively. These phases are characterised by single-crystal XRD and solid-state NMR spectroscopy, and their magnetic properties are reported.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | disordered structures, hybrid perovskite, metal-organic frameworks, paramagnetic NMR spectroscopy, perovskite phases |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 31 Jan 2020 09:37 |
| Last Modified: | 19 Jan 2023 00:05 |
| DOI: | 10.1002/chem.201803061 |
| Open Access URL: | https://www.osti.gov/biblio/1470673 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3072806 |
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